The IEEE International Workshop on Metrology for Automotive (METROAUTOMOTIVE 2022) aims to be a solid reference of the technical community to present and discuss the most recent results of scientific and technological research for the automotive industry, with particular emphasis to applications and new trends. Attention is paid, but not limited to, new technology for metrology-assisted production in automotive industry, sensors and associated signal conditioning for automotive, and calibration methods for electronic test and measurement for automotive. The program is designed to raise the interest of a wide group of researchers, operators and decision makers from metrology and automotive fields, by presenting the most innovative solutions in this field from the scientific and technological point of view. The Workshop covers all aspects of the segment focusing on electrical vehicles, connected autonomous cars and related mobility.